Chemistry Letters p. 359 - 362 (1994)
Update date:2022-09-26
Topics:
Ibata, Toshikazu
Shang, Muhong
Demura, Tetsuo
The reaction of p-chloronitrobenzene with N-methylpyrrolidine under high pressure gave demethylation product and ring opening products through quaternary ammonium chloride intermediate formed by the SNAr reaction.On the other hand, the reactions with N-methylpiperidine and N-methylmorpholine gave only demethylation products.The reactions of o-chloronitrobenzene and 2,4-dichloronitrobenzene with above amines gave similar results.
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