Journal of Organic Chemistry p. 3053 - 3061 (1980)
Update date:2022-09-26
Topics:
Schwartz, Jeffrey
Carr, Denise B.
Hansen, Robert T.
Dayrit, Fabian M.
The complex formed by reaction of Ni(acac)2 and DiBAH (1:1) catalyzes conjugate addition of dialkylaluminium acetylides to α,β enones; on hydrolysis, 3-alkynyl ketones are produced in high yield.Through this procedure conjugate addition of alkynyl groups
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