Structure and Chemistry of ?-Allyl Palladium Complexes from Steroids

DOI: 10.1039/P19810002504

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 2504 - 2508 (1981)

Update date:2022-07-30

Topics:

Authors:

Mahe, Christian

Patin, Henri

Hulle, Marie-Therese Van

Barton, Derek H.R.

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Article abstract of DOI:10.1039/P19810002504

The synthesis and structures of ?-allyl palladium complexes prepared from vitamins D₂ and D₃ and from ergosterol, 7,8-didehydrocholesterol, and 3-epi-cholesterol are described.The mechanism of palladisation is descussed as well as the transformation of the complexes into conjugated trienes or allylic alcohols.

Full text of DOI:10.1039/P19810002504

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