Journal of the Chemical Society. Perkin transactions I p. 2504 - 2508 (1981)
Update date:2022-07-30
Topics:
Mahe, Christian
Patin, Henri
Hulle, Marie-Therese Van
Barton, Derek H.R.
The synthesis and structures of ?-allyl palladium complexes prepared from vitamins D2 and D3 and from ergosterol, 7,8-didehydrocholesterol, and 3-epi-cholesterol are described.The mechanism of palladisation is descussed as well as the transformation of the complexes into conjugated trienes or allylic alcohols.
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