
Helvetica Chimica Acta p. 2036 - 2042 (2012)
Update date:2022-07-30
Topics:
Havare, Nizam
Plattner, Dietmar A.
Aryl epoxides undergo rearrangement and oxidative cleavage when reacted with in situ prepared hydroxy-λ3-iodane complexes. The presence of H2O plays a decisive role in steering the reaction path. A mechanistic scheme is proposed that accounts for the observed chemoselectivities. Copyright
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