Helvetica Chimica Acta p. 1947 - 1957 (1980)
Update date:2022-08-02
Topics:
Martin, Pierre
Steiner, Eginhard
Bellus, Daniel
The copper(I)-catalyzed free radical addition of halomethanes to acrylates and the addition of halogenated acetic acid derivatives to fluoro- or chloro-substituted ethylenes affords polyhalogenated butyric acid derivatives.Chlorides of these acids serve as precursors for haloketenes used in efficient syntheses of pyrethroids.
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