Chemistry Letters p. 75 - 76 (1999)
Update date:2022-08-03
Topics:
Sakurai, Hidehiro
Tanabe, Katsuhiko
Narasaka, Koichi
Chromium allyloxy(aryl)carbene complexes undergo formal [2,3]-or [1,2]-sigmatropic rearrangement by the catalytic use of Pd(PPh3)4 under CO atmosphere. The reaction is considered to proceed via palladium aroyl π-allyl complex, which is converted to the co
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