Benzocyclization of 2,4-Hexadienoic Acids. Synthesis of (R)-(-)-Curcuphenol Acetate

DOI: 10.1055/s-1987-27905

Source and publish data:

Synthesis p. 254 - 256 (1987)

Update date:2022-08-05

Topics:

Authors:

Murali, D.

Rao, G. S. Krishna

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Article abstract of DOI:10.1055/s-1987-27905

A simple and general benzocyclization sequence, useful in the conversion of α-methylene ketones/aldehydes 1a-f to phenolic acetates 6a-g via the dienoic acids 5a-g is presented.The technique has provided a new route to the terpenoids, thymol acetate (6f) and (R)-(-)-curcuphenol acetate (6g).

Full text of DOI:10.1055/s-1987-27905

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Product name:Phenol, 2-(1,5-dimethyl-4-hexenyl)-5-methyl-, acetate, (R)-

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