Asymmetric acylation of meso-diols with benzoyl halide in the presence of a chiral diamine

DOI: 10.1016/S0040-4039(97)10558-5

Source and publish data:

Tetrahedron Letters p. 397 - 400 (1998)

Update date:2022-08-03

Topics:

Authors:

Oriyama, Takeshi

Imai, Keisuke

Hosoya, Takeshi

Sano, Tomohumi

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Article abstract of DOI:10.1016/S0040-4039(97)10558-5

Nonenzymatic desymmetrization of cis-1,2-cyclohexanediol by the asymmetric acylation with achiral benzoyl chloride in the presence of a chiral diamine derived from (S)-proline took place to give monobenzoate in high optical yield.

Full text of DOI:10.1016/S0040-4039(97)10558-5

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Product name:1,2-Ethanediol, 1,2-diphenyl-, dibenzoate, (1R,2S)-

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