Journal of Organic Chemistry p. 271 - 273 (1980)
Update date:2022-09-26
Topics:
Harpp, David N.
Granata, Alessandro
Several sulfenyl thiocarbonates (RSSCO2CH3) have been decomposed with triphenylphosphine.In the case of R = alkyl, desulfurization takes place to give the S-alkyl thiocarbonate while in the case of R = aryl, a phosphonium salt is likely formed which on chromatographic workup on silica gel is converted to a thiol and triphenylphosphine oxide and sulfide.A mechanistic interpretation is offered.
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