Tetrahedron Letters p. 1205 - 1208 (1996)
Update date:2022-08-02
Topics:
Landais, Yannick
Parra-Rapado, Liliana
Epoxidation and cyclopropanation of 2-silyl-3-alkenols have been shown to occur with high 1,2-stereocontrol through substrate directable reactions. Both syn and anti epoxides are thus available from E and Z-allylsilanes. This contrasts with the results usually observed for allylsilanes lacking a coordinating group.
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