Epoxidation and cyclopropanation of 2-silyl-3-alkenols. A study of 1,2-asymmetric induction

DOI: 10.1016/0040-4039(95)02386-0

Source and publish data:

Tetrahedron Letters p. 1205 - 1208 (1996)

Update date:2022-08-02

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Authors:

Landais, Yannick

Parra-Rapado, Liliana

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Article abstract of DOI:10.1016/0040-4039(95)02386-0

Epoxidation and cyclopropanation of 2-silyl-3-alkenols have been shown to occur with high 1,2-stereocontrol through substrate directable reactions. Both syn and anti epoxides are thus available from E and Z-allylsilanes. This contrasts with the results usually observed for allylsilanes lacking a coordinating group.

Full text of DOI:10.1016/0040-4039(95)02386-0

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