Chemistry of Molybdenum. Part 2. Complexes of Molybdenum with 2-Aminocyclopent-1-ene-1-carbodithioate. Synthesis, Characterisation, and Electrochemical Studies.

DOI: 10.1039/DT9840000115

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Journal of the Chemical Society, Dalton Transactions p. 115 - 120 (1984)

Update date:2022-08-03

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Chaudhury, Muktimoy

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Article abstract of DOI:10.1039/DT9840000115

The chemistry of the bidentate (S,S^-) donor ligands 2-aminocyclopent-1-ene-1-carbodithioic acid (HL¹) and its N-alkylated derivatives 2), C4H9(HL³), or cyclo-C6H11(HL⁴)> with molybdenum in oxidation states +6 and +5 is described.The Mo^VI compounds are all cis-dioxo species.Reduction of 1)2> with excess HL¹ yields 1)3>, a monomeric Mo^V compound.The complexes are all intensely coloured due to a ligand-to-metal charge-transfer transition.Infrared electronic, e.s.r., magnetic, and electrochemical studies of these complexes are described.The results are discussed in terms of electronic structure and their relationship to the Mo centre in xanthine oxidase.

Full text of DOI:10.1039/DT9840000115

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Chemistry of Molybdenum. Part 2. Complexes of Molybdenum with 2-Aminocyclopent-1-ene-1-carbodithioate. Synthesis, Characterisation, and Electrochemical Studies.

DOI: 10.1039/DT9840000115

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Article abstract of DOI:10.1039/DT9840000115

Full text of DOI:10.1039/DT9840000115

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