
Tetrahedron Letters p. 4543 - 4546 (1994)
Update date:2022-07-30
Topics:
Schmalz, Hans-Guenther
Hessler, Erik
Bats, Jan W.
Duerner, Gerd
Complexation of (+)-L-arabinose-derived 2-benzyloxy-4-vinyl-2,5-dihydrofuran derivatives (8) with Fe2(CO)9 in ether proceeds diastereoselectively providing a (separable) mixture of the corresponding exo- and endo- η4-diene-Fe(CO)3 complexes 9 and 10 in a ratio of about 1 : 3.The relative (and absolute) configuration of the complexation products was determined by a combination of analytical methods (CD, NMR, X-ray).
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