First preparation of 5-allyl-1,3-oxazolidine-2-thione (napoleiferin), a natural homolog of 5-vinyl-1,3-oxazolidine-2-thione (goitrin)

Article abstract of DOI:10.1080/00397919908086147

The preparation of 5-allyl-1,3-oxazolidine-2-thione (napoleiferin) 5 via a practical synthesis of but-3-enal 2 and the key intermediate 1-aminopent- 4-en-2-ol 4 is described for the first time.

Full text of DOI:10.1080/00397919908086147

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Synthetic Communications: An
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First Preparation Of 5-
Allyl-1,3-Oxazolidine-2-Thione
(Napoleiferin), A Natural
Homolog Of 5-Vinyl-1,3-
Oxazolidine-2-Thione(Goitrin)
L. Latxague a & C. Gardrat b
a Laboratoire de Chimie Bio-Organique, Université
Victor Segalen Bordeaux 2., 146 Rue Léo Saignat
F-33076, Bordeaux Cedex, France
b Laboratoire de Chimie des Substances Végétales,
Institut du Pin, UniversitÉ Bordeaux I, 351 Cours de
la Libération F-33405, Talence Cedex, France
Version of record first published: 17 Sep 2007.
To cite this article: L. Latxague & C. Gardrat (1999): First Preparation Of 5-Allyl-1,3-
Oxazolidine-2-Thione (Napoleiferin), A Natural Homolog Of 5-Vinyl-1,3-Oxazolidine-2-
Thione(Goitrin), Synthetic Communications: An International Journal for Rapid
Communication of Synthetic Organic Chemistry, 29:10, 1627-1637
To link to this article: http://dx.doi.org/10.1080/00397919908086147
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