Journal of Organometallic Chemistry p. 365 - 376 (1991)
Update date:2022-08-03
Topics:
Ahn, Samyoung
Beck, Gerhard
Fehlhammer, Wolf Peter
Cr(CO)5CNCCl3 (3) reacts with phosphane (PPh3, PMe2Ph, PEt3) under aprotic conditions to give the Cr(CO)5-coordinated semiylidic isocyano(phosphoraneylidene)methylphosphoniumchlorides 4, 13.In the presence of (traces of) water, however, mainly (isocyano)methylphosphonium complexes 5,10, 11 are formed.In a side reaction, 3 is reduced to give Cr(CO)5CNCHCl2 which becomes the main product when the reaction is carried out in alcohol, acetone, or in the presence of a carboxylic acid (e.g. (PhCOOH).
Beijing Century Richap Chemistry Co.,Ltd
Contact:+86- 010-64455497
Address:Guannan County, Lianyungang City, Jiangsu Province, China
Contact:+86-134-5286-9121
Address:Add: Wing Tuck Commercial Centre, 177-183 Wing Lok Street, Hong Kong,
Hangzhou J&H Chemical Co., Ltd.
website:http://www.jhechem.com/
Contact:+86-571-87396432
Address:No.200 Zhenhua Rd.Xihu Industrial Park, Hangzhou 310030, China
Contact:86-25-58619180
Address:Nanjing High-Tech Zone 10 Xinghuo Road Pukou District Nanjing, Jiangsu 210061 The People's Republic of China
Liaoyang hengye Chemical Co., Ltd.
Contact:86-419-5850866
Address:North Old Xiaoxiao Road,Yantai District, Dengta, Liaoyang, Liaoning, China
Doi:10.1016/j.bmcl.2016.02.058
(2016)Doi:10.1039/b311197k
(2004)Doi:10.1039/d0ob00720j
(2020)Doi:10.1021/jm00187a013
(1979)Doi:10.1021/jo01323a010
(1979)Doi:10.1016/j.jorganchem.2005.10.048
(2006)
