
Journal of Organometallic Chemistry p. 189 - 202 (1983)
Update date:2022-08-04
Topics:
Burley, Joseph W.
Hutton, Ronald E.
Jolley, Michael R.J.
Groenenboom, Cornelis J.
(β-Carboalkoxyethyl)tin trihalides and bis(β-carboalkoxyethyl)tin dihalides react with metallic zinc to give mixtures of the corresponding tris(β-carboalkoxyethyl)tin halides and the tetra(β-carboalkoxyethyl)tins.Bis(β-carboalkoxyethyl)tin diacetates react with metallic zinc to give only the corresponding tetra(β-carboalkoxyethyl)tin compounds.The mechanisms of these reactions are discussed.Conversion of the bis(β-carboalkoxyethyl)tin dihalides into the tris(β-carboalkoxyethyl)tin halides is believed to occur by a two-step process, with the tetra(β-carboalkoxyethyl)tin compounds as intermediate products.The 270 MHz NMR spectra of the (β-carbobutoxyethyl)tin compounds are presented.
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