Reactions of 1,3-Thiazole-5(4H)-thiones with Grignard- and Organolithium Compounds: Carbophilic and Thiophilic Additions

DOI: 10.1002/hlca.19860690404

Source and publish data:

Helvetica Chimica Acta p. 773 - 785 (1986)

Update date:2022-08-04

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Authors:

Jenny, Christjohannes

Heimgartner, Heinz

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Article abstract of DOI:10.1002/hlca.19860690404

Organolithium compounds and 1,3-thiazole-5(4H)-thiones 9 reacted via thiophilic addition on the exocyclic S-atom.The intermediate anion E has been trapped by protonation to give 12 and by alkylation to yield 16, respectively (Schemes 5 and 6).In competiti

Full text of DOI:10.1002/hlca.19860690404

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