Macromolecules p. 4596 - 4599 (2011)
Update date:2022-08-04
Topics:
Zhang, Kai
Tieke, Bernd
π-Conjugated monomers and polymers containing benzodifuranone units in the main chain were prepared. Polymers were obtained using palladium-catalyzed Suzuki and Stille polycondensation reactions of dibromo-substituted benzodifuranone derivatives with either dihexylfluorene diboronester or bis(trimethylstannyl)thiophene. The optical and electronic properties were investigated using UV/vis absorption spectroscopy and cyclic voltammetry. It was found that the polymers show very broad absorption bands with a high extinction coefficient up to 32-500 L mol-1 cm-1. The polymers also show reversible redox behavior, giving small HOMO-LUMO gaps up to 1.30 eV with strong donor-acceptor character.
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