Bulletin of the Chemical Society of Japan p. 2569 - 2572 (1981)
Update date:2022-08-03
Topics:
Uosaki, Yasuhiro
Nakahara, Masaru
Osugi, Jiro
EDA-complex formation and 1,4-cycloaddition of tetracyanoethylene (TCNE) with styrene, α-methylstyrene, 1,1-diphenylethylene, cis-stilbene, and trans-stilbene were studied spectrophotometrically in chloroform at 25 deg C.Formation constants of the EDA complexes were found to be in the order, trans-stilbene above styrene above α-methylstyrene above cis-stilbene above 1,1-diphenylethylene.The difference in the formation constants was discussed in terms of both electronic and steric effects of the donors studied. α-Methylstyrene and 1,1-diphenylethylene underwent thermal cycloaddition to TCNE faster than styrene.It is suggested that some charge separation took place in the transition state.The fact that trans- and cis-stilbenes do not react with TCNE was explained in terms of the difference in stability of the 1,4-cycloadducts estimated from the 1,4-bislocalization energy obtained by Dewar's perturbation molecular orbital method.
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