A facile chemoenzymatic route to optically active 4,5-disubstituted-2E-hexenoate derivastives. II

DOI: 10.1248/cpb.41.680

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Chemical and Pharmaceutical Bulletin p. 680 - 684 (1993)

Update date:2022-07-30

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Authors:

Akita Akita

Umezawa Umezawa

Takano Takano

Oishi Oishi

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Article abstract of DOI:10.1248/cpb.41.680

The reaction of (±) methyl 4,5-trans-epoxy-(2E)-hexenoate (1) with nucleophiles having heteroatoms in the presence of BF₃ · Et₂O gave the 4,5-anti-5-hydroxy-4- and/or 2,5-anti-5-hydroxy-2-substituted products. Among them, the (±)-4,5

Full text of DOI:10.1248/cpb.41.680

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