
Tetrahedron Letters p. 1751 - 1754 (1982)
Update date:2022-07-30
Topics:
Kende, Andrew S.
Roth, Bruce
Kubo, Isao
A stereospecific sequence from the octalindione 2 leads in 21 steps to the new insecticide ajugarin-IV.Formation of the butenolide portion is conveniently achieved from acid 21 by sucessive use of the reagents tris(trimethylsiloxy)ethylene and ketenylidenetriphenylphosphorane.
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Doi:10.1021/jo00191a032
(1984)Doi:10.1016/0022-328X(96)06314-0
(1996)Doi:10.3987/R-1986-05-1231
(1986)Doi:10.1002/cctc.201402867
(2015)Doi:10.1021/ol802241h
(2008)Doi:10.1021/jo801338t
(2008)