Synthesis of polysubstituted 1,4-diazacycloheptan-5-ones. 1. Synthesis and conformational investigation of polysubstituted 4-piperidones

Article abstract of DOI:10.1023/A:1002820816850

A series of tri- and tetrasubstituted 4-piperidones and their bicyclic analogs has been synthesized. It was established by ¹H NMR spectroscopy that all the piperidones obtained have the chair conformation in solution with equatorially disposed

Full text of DOI:10.1023/A:1002820816850

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ꢀꢈꢀꢁꢂꢀꢃꢀꢎꢈꢄꢅꢅꢍꢌꢄꢀꢅꢆꢆꢀꢇꢂ ꢃꢀꢅꢆꢀꢇꢄ ꢃꢀꢄꢅꢅ ꢀꢀꢉꢀꢁꢂꢀꢃꢀꢎꢈꢏꢐꢂꢑꢒꢆꢀꢇꢂꢃꢃꢀꢇꢄꢃꢃꢀꢄꢀꢅꢁ
ꢃ
ꢃ
ꢀꢊꢀꢁꢂꢀꢃꢀꢓꢈꢔꢂꢈꢎꢈꢏꢐꢂꢑꢒꢆꢀꢇꢂ ꢃꢀꢇꢄꢃꢃꢀꢄꢀꢅꢁ ꢀꢀꢋꢀꢁꢂꢀꢃꢀꢎꢈꢕꢖꢗꢘꢙꢑꢒꢆꢀꢇꢂꢃꢃꢀꢇꢄꢃꢃꢀꢄꢀꢅꢁ
ꢃ
ꢀꢌꢀꢁꢂꢀꢃꢀꢎꢈꢕꢖꢗꢘꢙꢑꢒꢆꢀꢇꢂ ꢃꢀꢇꢄ ꢃꢀꢄꢅꢅ ꢀꢀꢍꢀꢁꢂꢀꢃꢀꢉꢈꢄꢅꢅꢌꢄꢀꢅꢆꢆꢀꢇꢂ ꢃꢀꢇꢄ ꢃꢀꢄꢀꢅꢁ
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ꢃ
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ꢀꢎꢀꢁꢂꢀꢃꢀꢎꢈꢍꢄꢋꢌꢄꢀꢅꢆꢆꢀꢇꢂ ꢃꢀꢇꢄꢃꢃꢀꢄꢀꢅꢁ ꢀꢀꢏꢀꢁꢂꢀꢃꢀꢃꢈꢍꢄꢋꢌꢄꢀꢅꢆꢆꢀꢇꢂ ꢃꢀꢇꢄ ꢃꢀꢄꢀꢅꢁ
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@ꢈꢀ ꢑꢓꢉꢀ ꢀꢚꢀ (ꢒ!ꢀ ꢜ.ꢜꢇꢁ#ꢀ ꢊꢌꢉꢅꢑꢍꢁꢀ ꢏꢀ ꢌꢄꢌꢉꢍꢄꢎ ꢈꢉꢊꢀ ꢑꢓꢉꢀ ꢊꢄꢗꢈꢁꢇꢊꢀ ꢏꢀ ꢑꢓꢉꢀ ꢌꢄꢌꢉꢍꢄꢎ ꢈꢉꢀ ꢍꢄꢈꢗꢀ ꢌꢍ ꢑ ꢈꢊꢀ ꢁꢌꢌꢉꢁꢍꢉꢎꢀ ꢁꢊ
'ꢁꢍꢄ ꢖꢊꢀꢗꢍ ꢖꢌꢊꢀ ꢏꢀꢊꢄꢗꢈꢁꢇꢊꢀꢎꢉꢌꢉꢈꢎꢄꢈꢗꢀ ꢈꢀꢑꢓꢉꢀꢊꢖꢃꢊꢑꢄꢑꢖꢉꢈꢑꢔꢀD ꢍꢀꢑꢓꢉꢀꢑꢉꢑꢍꢁꢁꢍꢆꢇꢀꢎꢉꢍꢄ'ꢁꢑꢄ'ꢉꢊꢀꢜꢅꢊ ꢊ ꢊꢏꢊ!ꢊꢖꢊ"ꢊꢐꢊꢑꢀꢑꢙ ꢀꢎ ꢖꢃꢇꢉꢑꢊ
ꢙꢉꢍꢉꢀ ꢃꢊꢉꢍ'ꢉꢎꢀꢈꢉꢁꢍꢀ)ꢔ%ꢀꢁꢈꢎꢀ)ꢔ2ꢀꢌꢌꢐꢀꢙꢄꢑꢓꢀꢁꢀꢅ ꢖꢌꢇꢄꢈꢗꢀꢅ ꢈꢊꢑꢁꢈꢑꢀ ꢏꢀ%<ꢛ%%ꢀꢚꢂꢋꢀꢁꢊꢊꢄꢗꢈꢉꢎꢀꢃꢆꢀꢖꢊꢀꢑ ꢀꢑꢓꢉꢀꢌꢍ ꢑ ꢈꢊꢀꢁꢑꢀꢅꢁꢍꢃ ꢈ
ꢁꢑ ꢐꢊꢀꢜꢂꢁꢃ ꢜꢂꢄꢃ#ꢀꢁꢈꢎꢀꢜꢂꢅꢃ ꢜꢂꢆꢃ#ꢀꢍꢉꢊꢌꢉꢅꢑꢄ'ꢉꢇꢆꢔꢀ:ꢓꢉꢀꢁꢊꢊꢄꢗꢈꢐꢉꢈꢑꢀꢄꢊꢀꢃꢁꢊꢉꢎꢀ ꢈꢀꢑꢓꢉꢀꢏ ꢇꢇ ꢙꢄꢈꢗ8ꢀꢄꢈꢀꢑꢓꢉꢀꢀꢚꢀ(ꢒ!ꢀꢊꢌꢉꢅꢑꢍꢖꢐꢀ ꢏ
ꢅ ꢐꢌ ꢖꢈꢎꢀꢜꢖꢋꢀꢍꢉꢅ ꢍꢎꢉꢎꢀꢄꢈꢀꢎꢉꢖꢑꢉꢍꢁꢑꢉꢎꢀ.ꢒ*ꢕꢋꢀꢑꢓꢉꢀꢊꢄꢗꢈꢁꢇꢀꢁꢑꢀ)ꢔ6ꢀꢌꢌꢐꢀꢄꢊꢀꢎꢄꢊꢌꢇꢁꢆꢉꢎꢀꢁꢊꢀꢁꢀꢎ ꢖꢃꢇꢉꢑꢀ ꢏꢀꢎ ꢖꢃꢇꢉꢑꢊꢀ ꢅ ꢖꢌꢇꢄꢈꢗ
ꢅ ꢈꢊꢑꢁꢈꢑꢊꢀ%<ꢔ2ꢀꢁꢈꢎꢀ)ꢔ%ꢀꢚꢂ#ꢔꢀ:ꢓꢉꢀꢁꢎꢎꢄꢑꢄ ꢈꢁꢇꢀꢊꢌꢇꢄꢑꢑꢄꢈꢗꢀ ꢅꢅꢖꢍꢊꢀꢁꢊꢀꢁꢀꢍꢉꢊꢖꢇꢑꢀ ꢏꢀꢑꢓꢉꢀ'ꢄꢅꢄꢈꢁꢇꢀ(ꢛꢚꢀꢌꢍ ꢑ ꢈꢋꢀꢙꢓꢄꢅꢓꢀꢊꢄꢗꢈꢁꢇꢀꢓꢁꢊ
ꢑꢓꢉꢀꢊꢓꢁꢌꢉꢀ ꢏꢀꢁꢀꢌ ꢍꢇꢆꢀꢍꢉꢊ ꢇ'ꢉꢎꢀꢑꢍꢄꢌꢇꢉꢑꢀꢁꢑꢀ=ꢔ2ꢀꢌꢌꢐꢔꢀ@ꢈꢀꢁꢎꢎꢄꢑꢄ ꢈꢀꢑꢓꢉꢀꢊꢄꢗꢈꢁꢇꢀꢁꢑꢀ)ꢔ%ꢀꢌꢌꢐꢀꢄꢊꢀꢌꢍꢁꢅꢑꢄꢅꢁꢇꢇꢆꢀꢖꢈꢅꢓꢁꢈꢗꢉꢎꢀꢄꢈꢀꢙꢄꢎꢑꢓ
ꢁꢈꢎꢀꢐꢖꢇꢑꢄꢌꢇꢄꢅꢄꢑꢆꢔꢀ/ꢀꢊꢄꢐꢄꢇꢁꢍꢀꢌꢄꢅꢑꢖꢍꢉꢀꢙꢁꢊꢀ ꢃꢊꢉꢍ'ꢉꢎꢀꢄꢈꢀꢑꢓꢉꢀꢅꢁꢊꢉꢀ ꢏꢀꢅ ꢐꢌ ꢖꢈꢎꢀꢜ!ꢀꢉ'ꢉꢈꢀꢙꢓꢉꢈꢀꢖꢊꢄꢈꢗꢀꢎꢉꢖꢑꢉꢍ ꢅꢓꢇ ꢍ ꢏ ꢍꢐꢔ
/ꢊꢊꢄꢗꢈꢐꢉꢈꢑꢀ ꢏꢀꢑꢓꢉꢀꢊꢄꢗꢈꢁꢇꢊꢀꢏ ꢍꢀꢑꢓꢉꢀꢎꢄꢐꢉꢑꢓꢆꢇꢀꢎꢄꢁꢍꢆꢇꢀꢎꢉꢍꢄ'ꢁꢑꢄ'ꢉꢊꢀꢜ#ꢊꢉꢊ$ꢊꢕꢀꢙꢁꢊꢀꢏꢁꢅꢄꢇꢄꢑꢁꢑꢉꢎꢀꢃꢆꢀꢑꢓꢉꢀꢌꢍꢉꢊꢉꢈꢅꢉꢀ ꢏ
ꢅ ꢖꢌꢇꢄꢈꢗꢀꢄꢈꢑꢉꢍꢁꢅꢑꢄ ꢈꢊꢀ ꢏꢀꢑꢓꢉꢀ=ꢛꢚ 2ꢛꢚ#ꢀꢌꢍ ꢑ ꢈꢊꢀꢙꢄꢑꢓꢀꢑꢓꢉꢀꢐꢉꢑꢓꢆꢇꢀꢗꢍ ꢖꢌꢀꢌꢍ ꢑ ꢈꢊꢋꢀꢁꢊꢀꢁꢀꢍꢉꢊꢖꢇꢑꢀ ꢏꢀꢙꢓꢄꢅꢓꢀꢑꢓꢉꢀꢏ ꢍꢐꢉꢍꢀꢙꢉꢍꢉ
ꢎꢄꢊꢌꢇꢁꢆꢉꢎꢀꢁꢊꢀꢐꢖꢇꢑꢄꢌꢇꢉꢑꢊꢀꢄꢈꢀꢑꢓꢉꢀꢊꢌꢉꢅꢑꢍꢁꢔꢀ:ꢓꢉꢀꢌꢍ ꢑ ꢈꢊꢀ ꢏꢀꢑꢓꢉꢀ(ꢛꢚꢀꢏꢍꢁꢗꢐꢉꢈꢑꢀꢁꢌꢌꢉꢁꢍꢀꢁꢊꢀꢎ ꢖꢃꢇꢉꢑꢊꢀꢙꢄꢑꢓꢀꢅ ꢖꢌꢇꢄꢈꢗꢀꢅ ꢈꢊꢑꢁꢈꢑ
%<ꢛ%%ꢀꢚꢂꢋꢀꢃꢖꢑꢀꢄꢈꢀꢎꢄꢏꢏꢉꢍꢉꢈꢅꢉꢀꢑ ꢀꢑꢓꢉꢀꢑꢉꢑꢍꢁꢁꢍꢆꢇꢀꢎꢉꢍꢄ'ꢁꢑꢄ'ꢉꢊꢀꢁꢍꢉꢀꢎꢄꢊꢌꢇꢁꢆꢉꢎꢀꢁꢑꢀꢓꢄꢗꢓꢉꢍꢀꢏꢄꢉꢇꢎꢀ =ꢔ2ꢛ=ꢔEꢀꢌꢌꢐ#ꢔ
@ꢈꢀꢑꢓꢉꢀꢀꢚꢀ(ꢒ!ꢀꢊꢌꢉꢅꢑꢍꢁꢀ ꢏꢀꢑꢓꢉꢀꢐ ꢈ ꢐꢉꢑꢓꢆꢇꢀꢎꢄꢁꢍꢆꢇꢀꢎꢉꢍꢄ'ꢁꢑꢄ'ꢉꢊꢀꢜ%ꢀꢁꢈꢎꢀꢜ&ꢀꢁꢇꢇꢀꢑꢓꢉꢀꢌꢍ ꢑ ꢈꢊꢀꢁꢍꢉꢀꢎꢄꢊꢌꢇꢁꢆꢉꢎꢀꢁꢊ
ꢊꢉꢌꢁꢍꢁꢑꢉꢀꢊꢄꢗꢈꢁꢇꢊꢀꢎꢖꢉꢀꢑ ꢀꢑꢓꢉꢀꢖꢈꢊꢆꢐꢐꢉꢑꢍꢄꢅꢁꢇꢀꢊꢑꢍꢖꢅꢑꢖꢍꢉꢔꢀ/ꢊꢊꢄꢗꢈꢐꢉꢈꢑꢀ ꢏꢀꢑꢓꢉꢀꢌꢍ ꢑ ꢈꢊꢀꢈꢉꢁꢍꢀꢑꢓꢉꢀ(Fꢚꢀꢏꢍꢁꢗꢐꢉꢈꢑꢀꢙꢁꢊꢀꢈ ꢑ
ꢎꢄꢏꢏꢄꢅꢖꢇꢑꢀ ꢎ ꢖꢃꢇꢉꢑꢀ ꢏꢀꢎ ꢖꢃꢇꢉꢑꢊꢀꢈꢉꢁꢍꢀ)ꢔ<ꢀꢌꢌꢐꢀꢁꢈꢎꢀꢁꢀꢎ ꢖꢃꢇꢉꢑꢀꢁꢑꢀ=ꢔEꢀꢌꢌꢐ#ꢀꢃꢖꢑꢀꢑꢓꢉꢀꢍꢉꢐꢁꢄꢈꢄꢈꢗꢀꢑꢓꢍꢉꢉꢀꢊꢄꢗꢈꢁꢇꢊꢀ 'ꢉꢍꢇꢁꢌꢀꢁꢈꢎꢀꢁ
ꢅ ꢍꢍꢉꢅꢑꢀ ꢎꢉꢊꢅꢍꢄꢌꢑꢄ ꢈꢀ ꢏꢀ ꢑꢓꢉꢀ ꢊꢌꢉꢅꢑꢍꢖꢐꢀ ꢃꢉꢅ ꢐꢉꢊꢀ ꢌ ꢊꢊꢄꢃꢇꢉꢀ ꢈꢇꢆꢀ ꢁꢏꢑꢉꢍꢀ ꢎ ꢖꢃꢇꢉꢀ ꢍꢉꢊ ꢈꢁꢈꢅꢉꢀ ꢉꢘꢌꢉꢍꢄꢐꢉꢈꢑꢊꢔꢀ :ꢓꢉꢀ ꢊꢄꢗꢈꢁꢇꢀ ꢏ
ꢐꢉꢑꢓꢄꢈꢉꢀꢌꢍ ꢑ ꢈꢀꢓꢁꢊꢀꢑꢓꢉꢀꢏ ꢍꢐꢀ ꢏꢀꢁꢀꢅ ꢐꢌꢇꢉꢘꢀꢐꢖꢇꢑꢄꢌꢇꢉꢑꢀꢎꢖꢉꢀꢑ ꢀꢅ ꢖꢌꢇꢄꢈꢗꢀꢙꢄꢑꢓꢀꢑꢓꢉꢀ'ꢄꢅꢄꢈꢁꢇꢀꢌꢍ ꢑ ꢈꢊꢔꢀ:ꢓꢉꢀꢌꢍ ꢑ ꢈꢊꢀ ꢏꢀꢑꢓꢉ
ꢗꢉꢐꢄꢈꢁꢇꢀꢖꢈꢄꢑꢀꢁꢍꢉꢀꢎꢄꢊꢌꢇꢁꢆꢉꢎꢀꢁꢊꢀꢑꢓꢉꢀ/Bꢀꢌꢁꢍꢑꢀ ꢏꢀꢁꢈꢀ/BGꢀꢊꢆꢊꢑꢉꢐꢀꢙꢄꢑꢓꢀ'ꢄꢅꢄꢈꢁꢇꢀꢅ ꢖꢌꢇꢄꢈꢗꢀꢅ ꢈꢊꢑꢁꢈꢑꢊꢀ%%ꢔ=ꢀꢁꢈꢎꢀ=ꢔ%ꢀꢚꢂꢔꢀ/ꢈ
ꢁꢈꢁꢇꢆꢊꢄꢊꢀꢅꢁꢍꢍꢄꢉꢎꢀ ꢖꢑꢀꢌꢍꢉ'ꢄ ꢖꢊꢇꢆꢀ ꢏꢀꢑꢓꢉꢀꢇꢄꢑꢉꢍꢁꢑꢖꢍꢉꢀ ꢈꢀ(ꢒ!ꢀꢊꢌꢉꢅꢑꢍ ꢊꢅ ꢌꢆꢀ ꢏꢀꢅ ꢐꢌ ꢖꢈꢎꢊꢀꢜꢅꢊ ꢊꢖꢊꢐꢀꢊꢓ ꢙꢉꢎꢀꢑꢓꢁꢑꢀꢑꢓꢉ
ꢌꢄꢌꢉꢍꢄꢎ ꢈꢉꢀꢍꢄꢈꢗꢀꢄꢊꢀꢄꢈꢀꢑꢓꢉꢀꢅꢓꢁꢄꢍꢀꢅ ꢈꢏ ꢍꢐꢁꢑꢄ ꢈꢀ$)ꢋ2&ꢔ
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ꢄꢁ
ꢅꢁ
ꢃ
ꢁꢂ
ꢄꢂ
ꢀ
ꢄꢀ
ꢁꢂ
ꢅꢂ
:ꢓꢉꢀ ꢌꢓꢉꢈꢆꢇꢀ ꢗꢍ ꢖꢌꢊꢀ ꢁꢍꢉꢀ ꢄꢈꢀ ꢁꢀ ꢑꢅꢂꢀ ꢎꢄꢊꢌ ꢊꢄꢑꢄ ꢈꢀ ꢍꢉꢇꢁꢑꢄ'ꢉꢀ ꢑ ꢀ ꢈꢉꢀ ꢁꢈ ꢑꢓꢉꢍꢋꢀ ꢁꢈꢎꢀ ꢑꢓꢉꢀ ꢊꢖꢃꢊꢑꢄꢑꢖꢉꢈꢑꢊꢀ !ꢀ ꢁꢍꢉꢀ ꢇ ꢅꢁꢑꢉꢎ
ꢉAꢖꢁꢑ ꢍꢄꢁꢇꢇꢆꢀ ꢍꢉꢇꢁꢑꢄ'ꢉꢀ ꢑ ꢀ ꢑꢓꢉꢀ ꢌꢄꢌꢉꢍꢄꢎ ꢈꢉꢀ ꢍꢄꢈꢗꢔꢀ :ꢓꢉꢀ ꢅ ꢖꢌꢇꢄꢈꢗꢀ ꢅ ꢈꢊꢑꢁꢈꢑꢊꢀ ꢏ ꢍꢀ ꢑꢓꢉꢀ ꢌꢍ ꢑ ꢈꢊꢀ ꢈꢀ ꢑꢓꢉꢀ ꢜꢂꢅꢃꢀ ꢁꢈꢎꢀ ꢜꢂꢁꢃꢀ ꢅꢁꢍꢃ ꢈ
ꢁꢑ ꢐꢊꢀꢓꢁ'ꢉꢀ'ꢁꢇꢖꢉꢊꢀ"ꢁꢁꢀ"ꢀ%<ꢛ%%ꢀꢚꢂꢋꢀꢙꢓꢄꢅꢓꢀꢅ ꢍꢍꢉꢊꢌ ꢈꢎꢊꢀꢑ ꢀꢑꢓꢉꢄꢍꢀ ꢄꢉꢊꢂꢀꢎꢄꢊꢌ ꢊꢄꢑꢄ ꢈꢀꢑ ꢀ ꢈꢉꢀꢁꢈ ꢑꢓꢉꢍꢔ
:ꢓꢉꢀꢍꢉꢊꢖꢇꢑꢊꢀ ꢏꢀꢑꢓꢉꢀꢅ ꢈꢏ ꢍꢐꢁꢑꢄ ꢈꢁꢇꢀꢁꢈꢁꢇꢆꢊꢄꢊꢀꢃꢆꢀ(ꢒ!ꢀꢊꢌꢉꢅꢑꢍ ꢊꢅ ꢌꢆꢀꢙꢉꢍꢉꢀꢅ ꢈꢏꢄꢍꢐꢉꢎꢀꢃꢆꢀGꢛꢍꢁꢆꢀꢊꢑꢍꢖꢅꢑꢖꢍꢉꢀ ꢏ
+ꢋ=ꢋ2ꢋEꢛꢑꢉꢑꢍꢁꢌꢓꢉꢈꢆꢇꢛ)ꢛꢌꢄꢌꢉꢍꢄꢎ ꢈꢉꢀ ꢜꢅ#ꢔꢀ:ꢓꢉꢀꢊꢄꢘꢛꢐꢉꢐꢃꢉꢍꢉꢎꢀꢍꢄꢈꢗꢀꢄꢊꢀꢄꢈꢀꢁꢀꢅꢓꢁꢄꢍꢀꢅ ꢈꢏ ꢍꢐꢁꢑꢄ ꢈꢀꢁꢈꢎꢀꢑꢓꢉꢀꢌꢓꢉꢈꢆꢇꢀꢗꢍ ꢖꢌꢊꢀꢁꢍꢉ
ꢎꢄꢊꢌ ꢊꢉꢎꢀꢄꢈꢀꢉAꢖꢁꢑ ꢍꢄꢁꢇꢀꢌ ꢊꢄꢑꢄ ꢈꢊꢀꢍꢉꢇꢁꢑꢄ'ꢉꢀꢑ ꢀꢑꢓꢉꢀꢌꢄꢌꢉꢍꢄꢎ ꢈꢉꢀꢍꢄꢈꢗꢀ$E&ꢔ
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ꢄꢊ ꢐꢉꢍꢊꢀ ꢙꢄꢑꢓꢀ ꢁꢈꢀ ꢉAꢖꢁꢑ ꢍꢄꢁꢇꢀ ꢌ ꢊꢄꢑꢄ ꢈꢀ ꢏꢀ ꢊꢖꢃꢊꢑꢄꢑꢖꢉꢈꢑꢊꢀ ꢁꢍꢉꢀ ꢏ ꢍꢐꢉꢎꢀ ꢁꢊꢀ ꢌꢍ ꢎꢖꢅꢑꢊꢀ ꢏꢀ ꢑꢓꢉꢀ ꢒꢁꢈꢈꢄꢅꢓꢀ ꢍꢉꢁꢅꢑꢄ ꢈꢔꢀ :ꢓꢉꢀ ꢊꢄꢘꢛ
ꢐꢉꢐꢃꢉꢍꢉꢎꢀꢍꢄꢈꢗꢀꢑꢓꢉꢍꢉꢏ ꢍꢉꢀꢓꢁꢊꢀꢑꢓꢉꢀꢅꢓꢁꢄꢍꢀꢅ ꢈꢏ ꢍꢐꢁꢑꢄ ꢈꢔ
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ꢃ
ꢀꢁ
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ꢃ
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ꢄꢅ
ꢂ
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ꢄꢅꢂꢃꢆ
ꢄꢅ
ꢁ
ꢃ
ꢄꢅ
ꢁꢃ
ꢂ
ꢄꢅ
ꢄ
ꢃ
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ꢑꢓꢉꢍꢐ ꢎꢆꢈꢁꢐꢄꢅꢁꢇꢇꢆꢀ ꢐ ꢊꢑꢀ ꢁꢎ'ꢁꢈꢑꢁꢗꢉ ꢖꢊꢀ ꢅ ꢐꢌ ꢖꢈꢎꢀ ꢐꢖꢊꢑꢀ ꢁꢅꢅꢖꢐꢖꢇꢁꢑꢉꢔꢀ @ꢈꢀ ꢖꢍꢀ ꢅꢁꢊꢉꢀ ꢑꢓꢉꢀ ꢄꢈꢑꢉꢍꢐꢉꢎꢄꢁꢑꢉꢀ ꢅ ꢐꢌ ꢖꢈꢎꢀ ꢔꢋ
ꢓꢁ'ꢄꢈꢗꢀꢑꢓꢉꢀꢊꢑꢉꢍꢉ ꢅꢓꢉꢐꢄꢊꢑꢍꢆꢀꢄꢈꢎꢄꢅꢁꢑꢉꢎꢀꢄꢈꢀꢑꢓꢉꢀꢊꢅꢓꢉꢐꢉꢋꢀꢄꢊꢀꢅ ꢈꢏ ꢍꢐꢁꢑꢄ ꢈꢁꢇꢇꢆꢀHꢌꢍꢉ ꢍꢗꢁꢈꢄꢂꢉꢎHꢀꢏ ꢍꢀꢑꢓꢉꢀꢅꢆꢅꢇꢄꢂꢁꢑꢄ ꢈꢀꢊꢑꢁꢗꢉ
ꢙꢓꢄꢅꢓꢀꢄꢈꢅꢍꢉꢁꢊꢉꢊꢀꢑꢓꢉꢀꢍꢁꢑꢉꢔꢀ:ꢓꢉꢀꢊꢉꢅ ꢈꢎꢀꢌ ꢊꢊꢄꢃꢇꢉꢀꢎꢄꢁꢊꢑꢉꢍꢉ ꢐꢉꢍꢀꢔꢀꢐꢖꢊꢑꢀꢗꢄ'ꢉꢀꢌꢍ ꢎꢖꢅꢑꢊꢀ ꢏꢀꢈ ꢈꢅꢆꢅꢇꢄꢅꢀꢌ ꢇꢆꢐꢉꢍꢄꢅꢀꢊꢑꢍꢖꢅꢑꢖꢍꢉꢔ
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ꢐ ꢇꢉꢅꢖꢇꢉꢀ ꢏꢀꢁꢇꢎꢉꢓꢆꢎꢉꢀꢙꢄꢑꢓꢀꢅ ꢐꢌ ꢖꢈꢎꢀꢔꢊꢀꢇꢉꢁꢎꢄꢈꢗꢀꢑ ꢀꢑꢓꢉꢀꢅꢆꢅꢇꢄꢅꢀꢅ ꢐꢌ ꢖꢈꢎꢋꢀꢐꢖꢊꢑꢀꢌꢍ ꢅꢉꢉꢎꢀꢙꢄꢑꢓꢀꢑꢓꢉꢀꢏ ꢍꢐꢁꢑꢄ ꢈꢀ ꢏꢀꢑꢓꢉ
ꢐꢄꢈꢄꢐꢁꢇꢇꢆꢀꢊꢑꢍꢁꢄꢈꢉꢎꢀꢌꢄꢌꢉꢍꢄꢎ ꢈꢉꢋꢀꢙꢓꢄꢅꢓꢀꢉꢘꢌꢇꢁꢄꢈꢊꢀꢑꢓꢉꢀꢏ ꢍꢐꢁꢑꢄ ꢈꢀꢉꢘꢅꢇꢖꢊꢄ'ꢉꢇꢆꢀ ꢏꢀꢄꢊ ꢐꢉꢍꢀ'ꢁ
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ꢝꢉꢑ ꢈꢉꢀꢄꢈꢀꢑꢓꢉꢀꢅ ꢖꢍꢊꢉꢀ ꢏꢀꢑꢓꢉꢀꢍꢉꢁꢅꢑꢄ ꢈꢔꢀ@ꢈꢀꢑꢓꢉꢀꢀꢚꢀ(ꢒ!ꢀꢊꢌꢉꢅꢑꢍꢁꢀ ꢏꢀ ꢈꢅꢉꢀꢍꢉꢅꢍꢆꢊꢑꢁꢇꢇꢄꢂꢉꢎꢀꢅ ꢐꢌ ꢖꢈꢎꢀꢜꢅꢋꢀꢄꢈꢀꢁꢎꢎꢄꢑꢄ ꢈꢀꢑ ꢀꢑꢓꢉ
ꢊꢄꢗꢈꢁꢇꢊꢀꢅ ꢍꢍꢉꢊꢌ ꢈꢎꢄꢈꢗꢀꢑ ꢀꢑꢙ ꢀꢑꢆꢌꢉꢊꢀ ꢏꢀꢈ ꢈꢛꢉAꢖꢄ'ꢁꢇꢉꢈꢑꢀꢌꢍ ꢑ ꢈꢊꢀ ꢏꢀꢑꢓꢉꢀꢌꢄꢌꢉꢍꢄꢎ ꢈꢉꢀꢍꢄꢈꢗꢋꢀꢑꢓꢉꢍꢉꢀꢙꢉꢍꢉꢀꢁꢇꢊ ꢀꢌꢍꢉꢊꢉꢈꢑꢀꢁꢈꢀ/B
ꢊꢆꢊꢑꢉꢐꢀ ꢏꢀꢑꢙ ꢀꢌꢍ ꢑ ꢈꢊꢀꢁꢑꢀ=ꢔ2ꢀꢌꢌꢐꢋꢀꢑꢙ ꢀꢎ ꢖꢃꢇꢉꢑꢊꢀꢙꢄꢑꢓꢀꢅ ꢖꢌꢇꢄꢈꢗꢀꢅ ꢈꢊꢑꢁꢈꢑꢀ%<ꢔ%ꢀꢚꢂꢀꢁꢑꢀ)ꢔEꢀꢁꢈꢎꢀ2ꢔ<ꢀꢌꢌꢐꢋꢀꢁꢈꢎꢀꢁꢀꢊꢄꢈꢗꢇꢉꢑꢀꢁꢑ
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: ꢀꢌꢍꢉꢌꢁꢍꢉꢀ ꢑꢓꢉꢍꢀ=ꢋ2ꢛꢎꢄꢁꢇꢝꢆꢇꢛꢊꢖꢃꢊꢑꢄꢑꢖꢑꢉꢎꢀꢌꢄꢌꢉꢍꢄꢎ ꢈꢉꢊꢀꢙꢉꢀꢁꢑꢑꢉꢐꢌꢑꢉꢎꢀꢑ ꢀꢖꢊꢉꢀꢅꢆꢅꢇꢄꢅꢀꢝꢉꢑ ꢈꢉꢊꢀꢁꢊꢀꢑꢓꢉꢀꢅꢁꢍꢃ ꢈꢆꢇ
ꢅ ꢐꢌ ꢈꢉꢈꢑꢀ ꢄꢈꢀ ꢑꢓꢉꢀ ꢒꢁꢈꢈꢄꢅꢓꢀ ꢍꢉꢁꢅꢑꢄ ꢈꢔꢀ @ꢑꢀ ꢑꢖꢍꢈꢉꢎꢀ ꢖꢑꢀ ꢑꢓꢁꢑꢀ ꢈꢇꢆꢀ ꢈꢀ ꢖꢊꢄꢈꢗꢀ ꢅꢆꢅꢇ ꢓꢉꢘꢁꢈ ꢈꢉꢀ ꢙꢄꢑꢓꢀ 'ꢁꢍꢄ ꢖꢊꢀ ꢁꢍ ꢐꢁꢑꢄꢅ
ꢁꢇꢎꢉꢓꢆꢎꢉꢊꢀꢁꢈꢎꢀꢁꢐꢐ ꢈꢄꢖꢐꢀꢁꢅꢉꢑꢁꢑꢉꢀꢑꢓꢉꢀꢃꢄꢅꢆꢅꢇꢄꢅꢀꢅ ꢐꢌ ꢖꢈꢎꢊꢀ)ꢅꢝ%ꢀꢙꢉꢍꢉꢀꢊꢖꢅꢅꢉꢊꢊꢏꢖꢇꢇꢆꢀ ꢃꢑꢁꢄꢈꢉꢎꢔ
ꢂ
ꢃꢄ
ꢀ
ꢃꢄ
ꢁ
ꢀꢁꢀꢂ
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: ꢀꢁꢇꢇꢀꢁꢌꢌꢉꢁꢍꢁꢈꢅꢉꢊꢀꢁꢀꢊꢉꢍꢄꢉꢊꢀ ꢏꢀ ꢑꢓꢉꢍꢀꢌꢍ ꢅꢉꢊꢊꢉꢊꢀ ꢏꢀꢅ ꢈꢎꢉꢈꢊꢁꢑꢄ ꢈꢀꢁꢈꢎꢀꢊꢉꢇꢏꢛꢅ ꢈꢎꢉꢈꢊꢁꢑꢄ ꢈꢀꢅ ꢐꢌꢉꢑꢉꢀꢙꢄꢑꢓꢀꢑꢓꢉ
ꢒꢁꢈꢈꢄꢅꢓꢀ ꢍꢉꢁꢅꢑꢄ ꢈꢀ ꢄꢈꢀ ꢑꢓꢉꢀ ꢅꢁꢊꢉꢀ ꢏꢀ ꢅꢆꢅꢇꢄꢅꢀ ꢝꢉꢑ ꢈꢉꢊꢔꢀ :ꢓꢄꢊꢀ ꢄꢈꢅꢇꢖꢎꢉꢊꢀ ꢑꢓꢉꢀ ꢏ ꢍꢐꢁꢑꢄ ꢈꢀ ꢏꢀ ꢑꢆꢌꢉꢀ *ꢂ ꢎꢄꢁꢍꢆꢇꢄꢎꢉꢈꢉꢀ ꢎꢉꢍꢄ'ꢁꢑꢄ'ꢉꢊꢋ
ꢙꢓꢄꢅꢓꢀꢁꢍꢉꢀꢏꢁꢄꢍꢇꢆꢀꢊꢑꢁꢃꢇꢉꢀꢅ ꢐꢌꢁꢍꢉꢎꢀꢙꢄꢑꢓꢀꢑꢓꢉꢀꢁꢇꢄꢅꢆꢅꢇꢄꢅꢀꢁꢈꢁꢇ ꢗꢊꢔ
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ꢀ
ꢀ
ꢁ
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