Advanced Synthesis and Catalysis p. 2433 - 2437 (2012)
Update date:2022-08-04
Topics:
Hajra, Saumen
Ghosh, Rajib
Chakrabarti, Sagar
Ghosh, Amit
Dutta, Swarup
Dey, Tushar K.
Malhotra, Rajesh
Asijaa, Sonika
Roy, Subho
Dutta, Shantanu
Basu, Sourav
A highly enantioselective (up to 91% ee) rhodium-catalyzed asymmetric addition of arylboronic acids has been achieved leading to the challenging dihydro-3-nitronaphthalenes using one equivalent of phosphoramidite ligand to rhodium catalyst. A concise formal asymmetric synthesis of the dopamine D1 agonist, dihydrexidine was accomplished using the method. Copyright
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