Journal of the American Chemical Society p. 2218 - 2221 (1986)
Update date:2022-07-31
Topics:
Burkey, T. J.
Majewski, M.
Griller, D.
A photoacoustic technique was used to measure heats of free radical reactions.To illustrate the method, bond dissociation energies were measured for the Sn-H bond in n-Bu3SnH, for the C3-H bond in 1,4-cyclohexadiene, and for the C2-H bond in diethyl ether.Heats of formation of t-BuOPPh3 and t-BuOP(Bu-n)2 were determined, and the method was also used to measure quantum yields for the photolysis of di-tert-butyl peroxide and diphenyl disulfide.
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