Tetrahedron p. 1275 - 1276 (1980)
Update date:2022-08-04
Topics:
Bergman, Jan
Engman, Lars
TeCl4 and naphtalene, when heated to 110 deg C in the abscence of a solvent, yielded 2-naphtyltellurium trichloride (2), which on treatment with degassed Raney Ni afforded 2,2'-binaphthyl in excellent yield.Reaction of 2 with propene and cis-2-butene produced the corresponding 1:1 adducts, which however could not be coupled to 2-(2-chloroalkyl)naphthalenes with this reagent.
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