Formations of Novel Dimeric Cyclohexanone Oxime Compounds

Article abstract of DOI:10.1246/bcsj.57.2162

The structure of the dimeric oxime compound obtained by the reaction of 2-chlorocyclohexanone oxime or 1-chloro-2-nitrosocyclohexane dimer with stoichiometrical ammonia was established to be 14-oxa-7,15,16-triazatetracyclo<11.2.1.0^1,6.0^8,13>hexadecan-16-ol by spectroscopic methods and X-ray crystallography; the result leads to a revision of the previously proposed structure, bis(2-hydroxyiminocyclohexyl)amine.