Journal of Organic Chemistry p. 613 - 617 (1980)
Update date:2022-08-04
Topics:
Sato, Yoshiro
Yagi, Yoko
Koto, Masami
Deprotonation of benzyldimethyl<(triorganosilyl)methyl>ammonium halides (10) with sodium amide or n-butyllithium afforded silylated ylide intermediates 11, which were rearranged into N,N-dimethyl-2-<(triorganosilyl)methyl>benzylamines (13) accompanied by the formation of Sommelet-Hauser and Stevens rearrangement products (12 and 22).The ylide formation by the cleavage of carbon-silicon bonds also is discussed in the reaction of 10 with sodium amide and lithium aluminum hydride.
View MoreContact:+86-27-87204219, +86-27-87215023
Address:2402, HuiGu Space-time Building, 8 Forest Road, East Lake Hi-Tech Development Zone
Beijing Wisdom Chemicals Co., Ltd.
Contact:+86-10-52350335
Address:F2, BLDG 19, Liando Valley U, Majuqiao, Tongzhou District, Beijing, China
SHAANXI TOP PHARM CHEMICAL CO.LTD
Contact:+86-029-85733403
Address:No.108 ,west sector,south er huan,xi'an,china
LianYunGang Chiral Chemical(CHINA) CO.,LTD
Contact:+86-518-83616958 +86-519-82884848
Address:LianYunGang Chemical Industry Park (JiangSu)
Shenzhen ZheYi Chemicals Co.,LTD(Shanghai Branch)
Contact:+86-21-54159691
Address:Room1002,Building No.2, Lane 98 Bixiu Road,Minhang District, Shanghai,China 201100
Doi:10.1016/S0040-4039(01)93967-X
(1979)Doi:10.1021/ja01613a086
(1955)Doi:10.1021/ic50207a014
(1980)Doi:10.1021/jo01295a032
(1980)Doi:10.1016/S0022-328X(00)83500-7
(1980)Doi:10.1021/om0498089
(2004)
