Journal of the Chemical Society. Chemical communications p. 686 - 688 (1981)
Update date:2022-07-30
Topics:
Hamilton, Robert
Mitchell, Thomas R. B.
McIlgorm, Edward A.
Rooney, John J.
McKervey, M. Anthony
The olefinic products arising from the oxidative addition at ambient temperatures of 2,2,6,6-tetramethylcyclohex-1-yl toluene-p-sulphonate to (PPh3)2CoBr2, (PPh3)2NiBr2, and hydroxo-cobalamin, all reduced with sodium borohydride, or to (Me)2CuLi, provide firm evidence for a novel mechanism of the 1,2-bond shift rearrangements catalysed by vitamin B12 coenzyme.
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