Asymmetric Synthesis of Optically Active β-Substituted Ketones by Highly Enantioselective Catalytic Conjugate Addition of Dialkylzinc Reagents to Enones using a Catalyst System of Nickel(II)-Chiral Ligand-Achiral Ligand in Acetonitrile/Toluene

DOI: 10.1039/c39890000516

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Journal of the Chemical Society. Chemical communications p. 516 - 517 (1989)

Update date:2022-08-05

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Authors:

Soai, Kenso

Hayasaka, Tomoiki

Ugajin, Shoji

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Article abstract of DOI:10.1039/c39890000516

Highly enantioselective conjugate addition of dialkylzinc reagents to aryl substituted enones using Ni(II)-bipyridyl-chiral ligand in acetonitrile (MeCN)/toluene as an in situ prepared catalyst system affords β-substituted ketones in up to 90percent enant

Full text of DOI:10.1039/c39890000516

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