DETERMINATION DES SITES D'OXYDATION DES DERIVES DU α-D-GLUCOFURANOSE UTILISES COMME DONNEURS

Article abstract of DOI:10.1016/S0008-6215(00)83657-5

The sites of oxidation, by catalytic transfer of H, of derivatives of 1,2-O-isopropylidene-α-D-glucofuranose suggest a regiospecific reaction.Compounds having vicinal hydroxyl groups at C-5 and C-6, or at C-3 and C-5, are oxidized at OH-5, whereas compounds having two hydroxyl groups at C-3 and C-6 or three hydroxyl groups give first aldehydes and then lactones.