Carbohydrate Research p. 25 - 32 (1980)
Update date:2022-08-04
Topics:
Descotes, Gerard
Sinou, Denis
Praly, Jean-Pierre
The sites of oxidation, by catalytic transfer of H, of derivatives of 1,2-O-isopropylidene-α-D-glucofuranose suggest a regiospecific reaction.Compounds having vicinal hydroxyl groups at C-5 and C-6, or at C-3 and C-5, are oxidized at OH-5, whereas compounds having two hydroxyl groups at C-3 and C-6 or three hydroxyl groups give first aldehydes and then lactones.
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