On the Incidence of Internal Ion Pair Return during Solvolysis of sec-Alkyl Benzenesulfonates

Article abstract of DOI:10.1021/ja00312a068

For solvolyses of four sec-alkyl benzenesulfonates, in which the alkyl group is isopropyl (1), cyclopentyl(2), 2-adamantyl (3), and 3,3-dimethyl-2-butyl (4), in CF3COOH and selected other solvents, overall solvolysis rates and rates of equilibration of ex