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Competitive Cyclopropanation and Aromatization of an Intermediate of the Sommelet-Hauser Rearrangement

DOI: 10.1039/c39800000629

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 629 - 631 (1980)

Update date:2022-07-29

Topics:

Authors:

Robert, AlbertRobert, Albert

Lucas-Thomas, Marie-ThereseLucas-Thomas, Marie-Therese

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Article abstract of DOI:10.1039/c39800000629

The non-aromatic intermediate of the Sommelet-Hauser rearrangement of a stabilized methoxycarbonyl sulphur ylide gives not only the expected rearranged product, but also reacts with the starting ylide to give the corresponding cyclopropane.

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