Studies on 2-Aziridinecarboxylic Acid.III. Reaction of 1-Acyl-2-aziridinecarboxylic Acid Peptide with Amines

DOI: 10.1246/bcsj.53.283

Source and publish data:

Bulletin of the Chemical Society of Japan p. 283 - 284 (1980)

Update date:2022-08-02

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Authors:

Nakajima, Kiichiro

Tanaka, Takumi

Morita, Kaoru

Okawa, Kenji

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Article abstract of DOI:10.1246/bcsj.53.283

The reaction of Z-Gly-Azy-Gly-OBzl with amines was studied.With primary amines, the 1-acyl group (Z-Gly) of the aziridine peptide mainly migrated to the reactant amine with cleaving of the amide bond between glycine and aziridine, whereas aniline and diethylamine gave diaminopropionic acid derivatives via the ring opening reaction.

Full text of DOI:10.1246/bcsj.53.283

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