Journal of Organic Chemistry p. 5003 - 5005 (1991)
Update date:2022-08-04
Topics:
Ryu, Ilhyong
Kusano, Kazuya
Yamazaki, Hiroshi
Sonoda, Noboru
A novel method for the synthesis of unsymmetrical ketones via the free radical carbonylation of alkyl halides is described.The mechanism of the reaction involves the trapping of an alkyl free radical by CO, the addition of the acyl free radical so formed to an alkene, and termination of the reaction by the abstraction of a hydrogen atom from tributyltin hydride by the product acyl-substituted free radical.
View MoreYancheng Smiling Imp & Exp Co., Ltd.
Contact:+86-515-83173586
Address:Rm1207, BLD#03, Phoenix Plaza, Juheng Road, Yancheng, Jiangsu, P.R. China
Jiangsu Zenji Pharmaceuticals LTD
Contact:+86-025-83172562; +1-224-888-1133(USA)
Address:No.5 Xinmofan Road
Hangzhou LINGEBA Technology Co., Ltd.
Contact:+0086-571-87389059
Address:Office 1-913,NewYouth Plaza, GongShu Area, HangZhou,ZheJiang,P.R.China
Xinchang Yueding Chemical Co., Ltd.
Contact:86-571-56926323
Address:NO.90 BEIMENCHENGWAI CHENGGUAN TOWN XINCHANG
Contact:+86-(0)21-3770 9035
Address:Room 301, Building 2, Meijiabang Road 1508, Shanghai China
Doi:10.1016/j.tet.2013.02.080
(2013)Doi:10.1021/ol071347a
(2007)Doi:10.1016/j.poly.2003.12.018
(2004)Doi:10.1039/c2ob06878h
(2012)Doi:10.1002/jhet.5570160142
(1979)Doi:10.1021/ja01187a033
(1948)
