Journal of Organic Chemistry p. 5003 - 5005 (1991)
Update date:2022-08-04
Topics:
Ryu, Ilhyong
Kusano, Kazuya
Yamazaki, Hiroshi
Sonoda, Noboru
A novel method for the synthesis of unsymmetrical ketones via the free radical carbonylation of alkyl halides is described.The mechanism of the reaction involves the trapping of an alkyl free radical by CO, the addition of the acyl free radical so formed to an alkene, and termination of the reaction by the abstraction of a hydrogen atom from tributyltin hydride by the product acyl-substituted free radical.
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