Journal of the American Chemical Society p. 1641 - 1644 (1980)
Update date:2022-07-30
Topics:
Gu, Tai-Yin Yang
Weber, William P.
Dimethylsilylene reacts with oxetane to give high yields of allyloxydimethylsilane and 2,2-dimethyl-1-oxa-2-silacyclopentane.These products result from decomposition of an initial 1,2-zwitterionic intermediate which is formed by coordination of the electrophilic dimethylsilylene with the oxygen of oxetane.Similar results have been obtained from the reactions of dimethylsilylene with 2-methyloxetane, 2,2-dimethyloxetane, 3,3-dimethyloxetane, and 2-vinyloxetane.
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(1936)
