Journal of the Chemical Society. Perkin transactions I p. 781 - 786 (1991)
Update date:2022-08-04
Topics:
Din, Laily Bin
Meth-Cohn, Otto
Walshe, Nigel D. A.
Acetophenone in 25percent oleum is substituted by various alkyl radicals specifically in the para-position.The radicals used include cyclohexyl, 3-chloro-1-methylpropyl, 3-bromo-1-methylpropyl, 4-chloro-1-methylbutyl, 4-bromo-1-methylbutyl, 5-bromo-1-methylpentyl, 5-acetoxy-1-methylpentyl, 3-carboxy-1-methylpropyl, 4-carboxy-1-methylbutyl and 5-carboxy-1-methylpentyl.They were all generated by hydrogen atom abstraction at the radical position by dimethylaminium radicals, generated in turn from protonated dimethylchloramine and ferrous sulphate.Yields were generally poor to moderate but utilised simple conditions and cheap reagents.
View MoreTaizhou volsen chemical Co., Ltd
website:http://www.volsenchem.com
Contact:+86-576-88869393
Address:Jiaojiang District, Taizhou, Zhejiang, China.
Sichuan All Solid State Materials Co.,Ltd.
website:http://www.kydmaterials.com
Contact:0833-5603116
Address:Airport road Jiajiang county, Sichuan province,China
Contact:
Address:308# dongwu avenue dongxihu district wuhan city
Changsha Yihai Chemical Technology Co.,ltd
website:http://www.cs-yihai.com/
Contact:0731- 85620465
Address:Room 23005, unit 2, the northern building of Xiangsong international building , NO.259 Shaoshan Road , Changsha , Hunan, China.(mainland)
shanghai jinshan pharmaceutical Co.,Ltd
Contact:021-57363011，13681638167
Address:No. 7966 Tingfeng Road,Jinshan,Shanghai,China
Doi:10.1016/S0957-4166(02)00542-6
(2002)Doi:10.1021/jo9004348
(2009)Doi:10.1021/jo4018099
(2013)Doi:10.1021/ic025862a
(2003)Doi:10.1002/1521-3765(20021115)8:22<5094::AID-CHEM5094>3.0.CO;2-6
(2002)Doi:10.1016/S0031-9422(00)89935-5
(1971)
