Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 823 - 826 (1991)
Update date:2022-08-03
Topics:
Il'inskaya, L. V.
Kuznetsov, V. F.
Gasanov, R. G.
The reduction of 1,1,1,5-tetrachloropentane by toluene in the presence of the Fe(CO)5 or M(CO)6 (M = Cr, Mo, W) in conjunction with triphenylphosphine was investigated.It was shown that the chlorine-containing metal carbonyl intermediates formed in the process take part in the transfer of the chlorine atom to the benzyl radicals.It was shown that HMn(CO)5 is not the main intermediate responsible for the transfer of hydrogen by the chloroalkyl radicals, which are formed during the reduction of 1,3,3,5-tetrachloropentane by triethylsilane in the presence of Mn2(CO)10.
View MoreLINYI FUDE FINE CHEMICAL CO.,LTD
Contact:86-539-2361184
Address:YISHUI, LINYI,SAHNDONG,CHINA
Contact:86-27-84888681
Address:Wuhan economic & technology development zone
Nanjing Chemlin Chemical Co., Ltd.
website:http://www.echemlin.cn
Contact:+86-25-83697070
Address:Rm.902 Longyin Plaza, No. 217 Zhongshan Rd.(N) Nanjing 210009,China
Anhui Asahikasei Chemical Co., Ltd
Contact:86-551-4259770
Address:No. 88 Linquan Road Hefei Anhui China
website:http://www.tbbmed.com
Contact:86--21-50498136
Address:Room 6002, Building 7-1, No.160 Basheng Road,Pudong Area,Shanghai China
Doi:10.1139/cjc-2016-0358
(2017)Doi:10.1246/bcsj.56.2661
(1983)Doi:10.1021/jm00325a037
(1965)Doi:10.1055/s-2004-822362
(2004)Doi:10.1016/j.jfluchem.2003.11.001
(2004)Doi:10.1016/j.bmcl.2004.05.068
(2004)
