Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 823 - 826 (1991)
Update date:2022-08-03
Topics:
Il'inskaya, L. V.
Kuznetsov, V. F.
Gasanov, R. G.
The reduction of 1,1,1,5-tetrachloropentane by toluene in the presence of the Fe(CO)5 or M(CO)6 (M = Cr, Mo, W) in conjunction with triphenylphosphine was investigated.It was shown that the chlorine-containing metal carbonyl intermediates formed in the process take part in the transfer of the chlorine atom to the benzyl radicals.It was shown that HMn(CO)5 is not the main intermediate responsible for the transfer of hydrogen by the chloroalkyl radicals, which are formed during the reduction of 1,3,3,5-tetrachloropentane by triethylsilane in the presence of Mn2(CO)10.
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