Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 823 - 826 (1991)
Update date:2022-08-03
Topics:
Il'inskaya, L. V.
Kuznetsov, V. F.
Gasanov, R. G.
The reduction of 1,1,1,5-tetrachloropentane by toluene in the presence of the Fe(CO)5 or M(CO)6 (M = Cr, Mo, W) in conjunction with triphenylphosphine was investigated.It was shown that the chlorine-containing metal carbonyl intermediates formed in the process take part in the transfer of the chlorine atom to the benzyl radicals.It was shown that HMn(CO)5 is not the main intermediate responsible for the transfer of hydrogen by the chloroalkyl radicals, which are formed during the reduction of 1,3,3,5-tetrachloropentane by triethylsilane in the presence of Mn2(CO)10.
View MoreContact:0086 533 2282832
Address:Zibo，Shandong
website:http://www.acrospharmatech.com
Contact:+1-3234804688
Address:Flat/RM 1502,Easey Commercial building 253-261 Hennessy Road,Wanchai，HongKong
Xi'an Unique Electronic and Chemical Co., Ltd.
Contact:+86-029-88238008
Address:1703# B BUILDING WEST ELECTRONIC ZONE, XI'AN, CHINA
Changzhou Sunsheng Chem Co., Ltd
Contact:+1-(989)-854-0648
Address:No. 28 Yinshan Rd., Xixiashu Industrial Park
ShiJiaZhuang Dowell Chemical Co.,Ltd.
website:http://www.dowechem.com
Contact:+86-13463963265
Address:Xiyangling village, high tech Zone, Shijiazhuang，Hebei, China
Doi:10.1139/cjc-2016-0358
(2017)Doi:10.1246/bcsj.56.2661
(1983)Doi:10.1021/jm00325a037
(1965)Doi:10.1055/s-2004-822362
(2004)Doi:10.1016/j.jfluchem.2003.11.001
(2004)Doi:10.1016/j.bmcl.2004.05.068
(2004)
