Tetrahedron Letters p. 7457 - 7460 (1996)
Update date:2022-08-05
Topics:
Gamble, Mark P.
Giblin, Gerard M. P.
Montana, John G.
O'Brien, Peter
Ockendon, Timothy P.
Taylor, Richard J. K.
Sulfones and sulfoxides synthesised from methionine and homocysteine thiolactone have been cyclised to amino ketones using potassium bis(trimethylsilyl)amide. Ramberg-Backlund chemistry on one of the sulfones gave an amino cyclopentenone whereas acyclic α-amino ketones and anti-amino alcohols were obtained by Raney nickel desulfurisation of the sulfoxides.
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Doi:10.1039/c39800000070
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