Facile Synthesis of 2,5-Diacylthiophenes. II. The Reaction of Diketo Sulfides with 1,2-Diketones

DOI: 10.1246/bcsj.53.1187

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1187 - 1188 (1980)

Update date:2022-08-04

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Authors:

Miyahara, Yuji

Inazu, Takahiko

Yoshino, Tamotsu

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Article abstract of DOI:10.1246/bcsj.53.1187

The base-catalyzed reaction of diketo sulfides (RCOCH2)2S (R=phenyl, p-tolyl) with biacetyl or benzil have provided high yields of 2,5-diacetyltetrahydrothiophene-3,4-diol derivatives rather than the expected 2,5-diacylthiophenes.The diols have been trans

Full text of DOI:10.1246/bcsj.53.1187

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