Thallium in Organic Synthesis. 59. Alkaloid Synthesis via Intramolecular Nonphenolic Oxidative Coupling. Preparation of (+/-)-Ocoteine, (+/-)-Acetoxyocoxylonine, (+/-)-3-Methoxy-N-acetylnornantenine, (+/-)-Neolitsine, (+/-)-Kreysigine, (+/-)-O-Methylkreys

DOI: 10.1021/ja00541a021

Source and publish data:

Journal of the American Chemical Society p. 6513 - 6519 (1980)

Update date:2022-07-29

Topics: Intramolecular Preparation Alkaloid synthesis Thallium

Authors:

Taylor, Edward C.

Andrade, Juan G.

Rall, Gerhardus J.H.

McKillop, Alexander

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Article abstract of DOI:10.1021/ja00541a021

Reaction of 1,2-bis(3,4-dimethoxyphenyl)ethane, 1,3-bis(3,4-dimethoxyphenyl)propane, diveratryl ether, N-methyl-N-veratrylveratramide, and N-methylbis(3,4-dimethoxybenzyl)amine with thallium(III) trifluoroacetate (TTFA) and BF3.Et2O in CH2Cl2/TFA resulted

Full text of DOI:10.1021/ja00541a021

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