REACTION OF CARBOXYLATE SALTS WITH CYCLIC PHOSPHORAMIDATES : AMIDE BOND FORMATION BY PRIOR AMINE CAPTURE

DOI: 10.1016/S0040-4039(00)78585-6

Source and publish data:

Tetrahedron Letters p. 2705 - 2708 (1980)

Update date:2022-07-29

Topics:

Authors:

Wakselman, M.

Acher, F.

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Article abstract of DOI:10.1016/S0040-4039(00)78585-6

Tri- or tetraalkyl-ammonium carboxylates react with 2-alkylamino-2-oxo-1,3,2-benzodioxaphospholes at 25 deg C to give amides or peptides, probably by a nucleophilic attack on phosphorous followed by a cascade of intramolecular acyl transfer reaction.

Full text of DOI:10.1016/S0040-4039(00)78585-6

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