Chemistry of Heterocyclic Compounds p. 495 - 500 (1980)
Update date:2022-08-02
Topics:
Samsoniya, Sh. A.
Targamadze, N. L.
Kurkovskaya, L. N.
Kereselidze, Dzh. A.
Suvorov, N. N.
As expected, the 3 and 8 positions are the reaction centers of 1H,6H-pyrrolo<2,3-e>indole in the Vilsmeier-Haack and Mannich reactions.Diazo coupling takes place primarily in the 3 position and leads primarily to monosubstitution products. 6,8-Diacetyl-1H,6H-pyrrolo<2,3-e>indole and 1,8-diacetyl-1H,6H-pyrrolo<2,3-e>indole were isoleted from the acetylation products.
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