Journal of the Chemical Society. Chemical communications p. 1362 - 1364 (1982)
Update date:2022-09-26
Topics:
Lopusinski, Andrzej
Michalski, Jan
Potrzebowski, Mark
The thioxophosphoranesulphenyl bromides (1) act as ambident electrophiles towards alkenes and react, depending on the structure of the alkene, to give either the normal addition products -SC(R1)(R2)CR3(R4)(Br) or 1,2-dibromides and -disulphides.
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