Ambident Electrophilic Character of Thioxophosphoranesulphenyl Bromides =P(S)SBr. A Novel Observation of Electrophilic Addition to a Carbon-Carbon Double Bond

DOI: 10.1039/c39820001362

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1362 - 1364 (1982)

Update date:2022-09-26

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Authors:

Lopusinski, Andrzej

Michalski, Jan

Potrzebowski, Mark

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Article abstract of DOI:10.1039/c39820001362

The thioxophosphoranesulphenyl bromides (1) act as ambident electrophiles towards alkenes and react, depending on the structure of the alkene, to give either the normal addition products -SC(R¹)(R²)CR³(R⁴)(Br) or 1,2-dibromides and -disulphides.

Full text of DOI:10.1039/c39820001362

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