Ambident Electrophilic Character of Thioxophosphoranesulphenyl Bromides =P(S)SBr. A Novel Observation of Electrophilic Addition to a Carbon-Carbon Double Bond

DOI: 10.1039/c39820001362

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1362 - 1364 (1982)

Update date:2022-09-26

Topics:

Authors:

Lopusinski, Andrzej

Michalski, Jan

Potrzebowski, Mark

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39820001362

The thioxophosphoranesulphenyl bromides (1) act as ambident electrophiles towards alkenes and react, depending on the structure of the alkene, to give either the normal addition products -SC(R¹)(R²)CR³(R⁴)(Br) or 1,2-dibromides and -disulphides.

Full text of DOI:10.1039/c39820001362

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:bis-(O,O-2,2-dimethylpropylthiophosphoryl)disulfide

Cas No:74895-06-0

R&D Labs maybe for 74895-06-0

Jintan Jinnuo Chemical Co., Ltd.

Contact:+86-519-80199901

Address:Room 1804, Building 1, Huacheng Business Plaza, Jintan, Jiangsu, China
Beijing Cooperate Pharmaceutical Co.,Ltd

website:http://www.cooperate-pharm.com/

Contact:86-01060279497

Address:No.507,Building 4,Tianhua Street, Biomedicine industrial Base
SHANXI JINJIN CHEMICAL INDUSTRIAL CO.,LTD

website:http://www.jinjingroup.com

Contact:86-574-13989382828

Address:Economic And Technological Development Zone,Hejin?City,Shanxi Province?,China
Beijing Harmony Chemical Co., Ltd.

Contact:86-010-84956928

Address:Room 207, Jin feng he B building, No 8 Xin Jie Kou Wai Street, Xi Cheng District, Beijing,PRC. 10008
Lanling Hongchuang Flame Retardant Co., Ltd.

Contact:+86-531-68858132

Address:East Huafeichang Road, Cangshan County, Linyi, Shandong, China (Mainland)

Relevant to this article

Determining Essential Requirements for Fluorophore Selection in Various Fluorescence Applications Taking Advantage of Diverse Structure-Fluorescence Information of Chromone Derivatives

Doi:10.1021/acs.jmedchem.0c01508
(2021)
Fluorous phase-switching of pyridyl-tagged substrates/products

Doi:10.1021/ol048994b
(2004)
Cyclopeptide Alkaloids. Synthetic, Spectroscopic and Conformational Studies of Phencyclopeptine Model Compounds

Doi:10.1021/jo01312a001
(1980)
A Serendipitous Synthesis of Bis-Heterocyclic Spiro 3(2 H)-Furanones

Doi:10.1021/acs.joc.5b02350
(2016)
Oxidations with Cerium(IV) Sulfate: Intramolecular Cyclization of N-Benzyl-&β-aminoketones Yielding 4-Benzoyl-1,2,3,4-tetrahydroisoquinolines

Doi:10.1002/ardp.19873200715
(1987)
Copper activation of boronic acids: Factors affecting reactivity

Doi:10.1002/aoc.3144
(2014)

Article Doi