Rearrangement Chemistry of the α-Diazo Ketone Derived from 2,2,5,5-Tetramethylthiolane-3,4-dione

DOI: 10.1021/jo01311a062

Source and publish data:

Journal of Organic Chemistry p. 4804 - 4805 (1980)

Update date:2022-08-05

Topics: Carbene Insertion Wolff Rearrangement C-H Insertion

Authors:

Bolster, J.

Kellogg, Richard M.

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Article abstract of DOI:10.1021/jo01311a062

The α-diazo ketone of 2,2,5,5-tetramethylthiolane-3,4-dione undergoes both thermally and photochemically induced rearrangement; the chief product, a thietanone derivative, undergoes smooth and rapid photochemically induced fragmentation.

Full text of DOI:10.1021/jo01311a062

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