Chemistry of Heterocyclic Compounds p. 401 - 405 (1980)
Update date:2022-08-05
Topics:
Reznichenko
Shapkin
Popov
The cyclization of 1-(2,5-dihalophenylamino)-8-hydroxyanthraquinones or the corresponding 8-methoxycompounds in concentrated sulfuric acid has given derivatives of a new hexanuclear heterocyclic system -12H-benzo[m,n]chromeno [2,3,4-k, l]acridine. It has been shown that the double cyclization takes place initially through the closure of the pyridine ring with the formation of 9H-napth[3,2,1-k, l]acridine, the product of 1,9-cyclization. Under the reaction conditions the latter undergoes intramolecular aroxylation with the formation of a pyran ring under a-typical conditions.
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Doi:10.1002/jhet.4011
(2020)Doi:10.1002/jlcr.791
(2004)Doi:10.1016/S0040-4039(00)93652-9
(1980)Doi:10.1021/jo01313a027
(1980)Doi:10.1002/hlca.19800630302
(1980)Doi:10.1002/jps.2600690527
(1980)