Mechanistic studies of the transfer dehydrogenation of cyclooctane catalyzed by iridium bis(phosphinite) p-XPCP pincer complexes

DOI: 10.1021/ja048393f

Source and publish data:

Journal of the American Chemical Society p. 9330 - 9338 (2004)

Update date:2022-07-30

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Authors:

Goettker-Schnetmann, Inigo

Brookhart, Maurice

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Article abstract of DOI:10.1021/ja048393f

Reaction of bis(phosphinite) PCP iridium pincer complexes (p-XPCP)IrHCl (5a-f) [X = MeO (5a), Me (5b), H (5c), F (5d), C₆F₅ (5e), Ar^F(= 3,5-bis(trifluoromethyl)phenyl) (5f)] with NaOtBu in neat cyclooctane (COA) generates

Full text of DOI:10.1021/ja048393f

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