Journal of Organometallic Chemistry p. 283 - 292 (1980)
Update date:2022-08-02
Topics:
Chen, Loomis S.
Chen, Grace J.
Tamborski, Christ
Experimental conditions have now been developed whereby o-bromophenyl-lithium(II) may be prepared in excellent yields and used as an organometallic intermediate for the synthesis of a variety of ortho bromo substituted phenyl compounds (o-BrC6H4X).The thermal stability, decomposition products and reactions of II were studied.Reactions between II and a variety of substrates, e.g., CO2, dimethylformamide, fluorinated esters, hexafluorobenzene, and organosilicon chlorides were examined.
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