
Journal of Organic Chemistry p. 144 - 147 (1981)
Update date:2022-08-04
Topics:
England, David C.
Donald, Elaine A.
Weigert, Frank J.
Fluorinated α-pyrones 6 have been prepared from perfluoroacryloyl fluorides 1 and 2 by reaction with arylacetylenes and/or methyl ketones.Cyclobutenecarboxylates 8 have also been obtained from the reactions of 1 with acetylenes.The NMR spectrum of pyrone 6e shows unusually long-range fluorine-fluorine coupling.
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