Formal syntheses of N-trifluoroacetyl-L-acosamine and N-trifluoroacetyl-L-daunosamine from an achiral precursor, methyl sorbate

Article abstract of DOI:10.1248/cpb.43.171

N-Trifluoroacetyl-L-acosamine 20 and N-trifluoroacetyl-L-daunosamine 21 were formally synthesized from an achiral precursor, methyl sorbate 4, based on enzymatic chiral induction and diastereoselective 1,4-conjugated addition of benzylamine to the olefini

Full text of DOI:10.1248/cpb.43.171

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