Synthetic Communications p. 69 - 77 (1997)
Update date:2022-09-26
Topics:
Danieli, Bruno
Lesma, Giordano
Passarella, Daniele
Silvani, Alessandra
A mixture of dimethyl 1-benzyl-cis- and trans-piperidine-3,5-dicarboxylate is prepared in high yields from readily available starting materials, by a reliable procedure. The straightforward conversion of the mixture into the diastereomerically pure cis-isomer, a useful σ-symmetry intermediate for alkaloid synthesis, is also prescribed.
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