A New Radical Decarboxylation Reaction for the Conversion of Carboxylic Acids into Hydrocarbons

DOI: 10.1039/c39800000732

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 732 - 733 (1980)

Update date:2022-08-04

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Authors:

Barton, Derek H. R.

Dowlatshahi, Hussein A.

Motherwell, William B.

Villemin, Didier

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Article abstract of DOI:10.1039/c39800000732

The esters of trans-9-hydroxy-10-phenylthio- or -10-chloro-9,10-dihydrophenanthrene are smoothly reduced under neutral conditions by tri-n-butylstannane to furnish, by radical elimination, phenanthrene and the nor-hydrocarbon formed from decomposition of the corresponding acyloxy radical.

Full text of DOI:10.1039/c39800000732

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